Add shortcut with lxde or openbox
Edit file $HOME/.config/openbox/lxde-rc.xml and then add your shortcut in.
Example
Set Control+Winkey+F12
as shortcut for vim
<keybind key="C-W-F12">
<action name="Execute">
<command>/usr/local/bin/grkill</command>
</action>
</keybind>